Methylmagnesium iodide solution - 100ML

Description

3.0 M in diethyl ether

CAS Number 917-64-6

Linear Formula CH3MgI

Molecular Weight 166.24 

Application

Methylmagnesium iodide solution can be used:

•  To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.

•  In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.

•  To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.

•  In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.

Packaging

100, 800 mL in Sure/Seal™

Safety Information

Symbol GHS02, GHS05, GHS07

Signal word Danger

Hazard statements H225-H260-H314-H336

Precautionary statements P210-P223-P231 + P232-P261-P370 + P378-P422

Supplemental Hazard Statements May form explosive peroxides., Reacts violently with water.Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RIDADR UN 3399A 4.3(3) / PGI

WGK Germany 3

Flash Point(F) -40 °F

Flash Point(C) -40 °C