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Acids and Bases
Methylmagnesium chloride solution - 8L
Availablity:
In stock
Catalog/Part Number:
189901-8L
Brand:
MERCK
Supplier:
MERCK
Supplier Location:
GERMANY
Inventory Weight:
unavailable
Unit of Measurement:
Inventory Brochure:
unavailable
Catalog/Part Number:: 189901-8L
₦1,686,060.00
Description
3.0 M in THF
CAS Number 676-58-4
Linear Formula CH3MgCl
Molecular Weight 74.79
Application
Methylmagnesium chloride solution (3 M in THF) undergoes 1,3-addition with dialdose derived nitrones to form N-benzylhydroxylamines. The reductive cleavage of the N-O bond of these N-benzylhydroxylamines results in N-benzylaminosugars, which are key moieties of bioactive compounds. It can also react with Garner type aldehydes to form the corresponding secondary alcohols.
Packaging
4×25, 100, 800 mL in Sure/Seal™
8, 18 L in Kilo-Lab™
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Safety Information
Symbol GHS02
, GHS05
, GHS07
, GHS08
Signal word Danger
Hazard statements H225-H260-H302-H314-H335-H351
Precautionary statements P210-P231+232-P280-P370 + P378-P402 + P404-P403 + P235
Supplemental Hazard Statements May form explosive peroxides., Reacts violently with water.
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RIDADR UN 3399BC 4.3(3) / PGII
WGK Germany 3
Flash Point(F) 1.4 °F
Flash Point(C) -17 °C
Technical Specifications
Properties
Related Categories 25mL Sure/Seal Reagents, Acids & Bases, Alkyl, Aryl and Alkenyl - Grignard reagent, Bases, Chemical Synthesis,
Quality Level 200
autoignition temp. 609 °F
concentration 3.0 M in THF
density 1.013 g/mL at 25 °C
SMILES string C[Mg]Cl
InChI 1S/CH3.ClH.Mg/h1H3;1H;/q;;+1/p-1
InChI key RQNMYNYHBQQZSP-UHFFFAOYSA-M
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