364649-100ML

Availablity: In stock

Catalog/Part Number: 364649-100ML
Brand: MERCK
Supplier: MERCK
Supplier Location: GERMANY
Inventory Weight: unavailable
Unit of Measurement:
Inventory Brochure: unavailable

Catalog/Part Number:: 364649-100ML

₦95,700.00

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Description

General description

tert-Butylmagnesium chloride, an organomagnesium compound, is commonly known as Grignard reagent. It is a powerful carbon nucleophile mainly used for C-C bond formation.[4]

Application

tert-Butylmagnesium chloride (1.0 M in THF) has been used in the preparation of tert-butylsulfinyl chloride.[1]
It can be used in:
• Grignard metathesis reaction of 2,5-dibromo-3-hexylthiophene to form 2-bromo-5-magnesiobromo-3-hexylthiophene.[2]
• A key step for the asymmetric synthesis of sulfinyl transfer agents using cinchona alkaloids quinine and quinidine as chiral auxiliaries.[3]

Packaging

100, 800 mL in Sure/Seal™

Other Notes

Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and ocassional gentle swirling should redissolve the solid.

 

Catalog/Part Number: 364649-100ML Category:

Technical Specifications

Related Categories



Acids & BasesAlkyl, Aryl and Alkenyl - Grignard reagentBasesChemical SynthesisGrignard Reagents,
More...
Quality Level   200
concentration   1.0 M in THF
density   0.931 g/mL at 25 °C
SMILES string   CC(C)(C)[Mg]Cl
InChI   1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1
InChI key   ZDRJSYVHDMFHSC-UHFFFAOYSA-M

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